Polymerization of long chain alkyl glycidyl ethers: a platform for micellar gels with tailor-made melting points-Reference-Cited by-同舟云学术

Polymerization of long chain alkyl glycidyl ethers: a platform for micellar gels with tailor-made melting points

Published:2018 Issue:44 Volume:9 Page:5327-5338
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Verkoyen Patrick¹²³⁴,Johann Tobias¹²³⁴⁵,Blankenburg Jan¹²³⁴⁶,Czysch Christian¹²³⁴,Frey Holger¹²³⁴^ORCID

Affiliation:

1. Institute of Organic Chemistry

2. Johannes Gutenberg-University Mainz

3. 55099 Mainz

4. Germany

5. Max Planck Graduate Center

6. Graduate School Materials Science in Mainz

Abstract

Controlled polymerization of long-chain alkyl glycidyl ethers (AlkGE) under anionic ring opening conditions is enabled by the addition of 18-crown-6. Capitalizing on this strategy, highly amphiphilic block copolymers are prepared that form hydrogels with adjustable melting points.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2018/PY/C8PY01312H

Reference48 articles.

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3. Synthesis of Linear, Cyclic, Figure-Eight-Shaped, and Tadpole-Shaped Amphiphilic Block Copolyethers via t-Bu-P4-Catalyzed Ring-Opening Polymerization of Hydrophilic and Hydrophobic Glycidyl Ethers

4. Synthesis, Thermal Properties, and Morphologies of Amphiphilic Brush Block Copolymers with Tacticity-Controlled Polyether Main Chain

5. Association properties of poly(ethylene oxide) modified by pendant aliphatic groups

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