The copper sulfate hydration cycle. Crystal structures of CuSO4 (Chalcocyanite), CuSO4·H2O (Poitevinite), CuSO4·3H2O (Bonattite) and CuSO4·5H2O (Chalcanthite) at low temperature using non-spherical atomic scattering factors-Reference-Cited by-同舟云学术

The copper sulfate hydration cycle. Crystal structures of CuSO₄ (Chalcocyanite), CuSO₄·H₂O (Poitevinite), CuSO₄·3H₂O (Bonattite) and CuSO₄·5H₂O (Chalcanthite) at low temperature using non-spherical atomic scattering factors

Published:2022 Issue:12 Volume:46 Page:5479-5488
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Ibrahim Mukaila A.¹²^ORCID,Boeré René T.¹²^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of Lethbridge, Lethbridge, Canada

2. The Canadian Centre for Research in Advanced Fluorine Technologies (C-CRAFT), University of Lethbridge, Lethbridge, Canada

Abstract

Sky blue CuSO4·3H2O is the midpoint of the copper sulfate hydration cycle. The progression from colourless CuSO4 to bright blue CuSO4·5H2O is intimately linked to the relative number of sulfato versus aqua ligands coordinated to copper.

Funder

Natural Sciences and Engineering Research Council of Canada

University of Lethbridge

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ00169A

Reference53 articles.

1. Near 100% student yields with the "cycle of copper reactions" experiment

2. Decomposition of copper(II) sulfate pentahydrate: A sequential gravimetric analysis

3. Waters of Hydration of Cupric Hydrates: A Comparison between Heating and Absorbance Methods

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