Mechanistic investigation of a Ni-catalyzed electrochemical reductive cleavage of the α-O-4 bond in the lignin model compound benzyl phenyl ether-Reference-Cited by-同舟云学术

Mechanistic investigation of a Ni-catalyzed electrochemical reductive cleavage of the α-O-4 bond in the lignin model compound benzyl phenyl ether

Published:2023 Issue:23 Volume:25 Page:9720-9732
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Lin Fang¹²,Petrović Predrag V.²³^ORCID,Tse Ho-Yin²³^ORCID,Erythropel Hanno C.²³⁴^ORCID,Lam Jason Chun-Ho⁵^ORCID,Anastas Paul T.¹²³⁴⁶

Affiliation:

1. Department of Chemistry, Yale University, 225 Prospect St, New Haven, CT, USA

2. Center for Green Chemistry & Green Engineering at Yale, 370 Prospect St, New Haven, CT, USA

3. Yale School of the Environment, 195 Prospect St, New Haven, CT, USA

4. Department of Chemicals and Environmental Engineering, Yale University, 17 Hillhouse Ave, New Haven, CT, USA

5. City University of Hong Kong, School of Energy and Environment, Kowloon Tong, Hong Kong

6. Yale School of Public Health, 60 College St, New Haven, CT, USA

Abstract

The electrochemical reductive cleavage of the C–O bond in the lignin α-O-4 model compound benzyl phenyl ether (BPE) at room temperature was investigated using earth-abundant nickel as a catalyst in methanol.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/GC/D3GC01814H

Reference62 articles.

1. Designing for a green chemistry future

2. Greener Routes to Biomass Waste Valorization: Lignin Transformation Through Electrocatalysis for Renewable Chemicals and Fuels Production

3. Catalytic Transfer Hydrogenolysis of Lignin-Derived Aromatic Ethers Promoted by Bimetallic Pd/Ni Systems

4. Catalytic Lignin Depolymerization to Aromatic Chemicals

5. S.Vidal , Protecting groups: strategies and applications in carbohydrate chemistry , John Wiley & Sons , 2019

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