Boosting the mono-axial crystal field in stable high-coordinate Dy(<scp>iii</scp>) single-ion magnets by substitution of the phenoxy axial ligand-Reference-Cited by-同舟云学术

Boosting the mono-axial crystal field in stable high-coordinate Dy(iii) single-ion magnets by substitution of the phenoxy axial ligand

Published:2023 Issue:30 Volume:52 Page:10465-10471
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Ben¹,Zhou Yang¹,Dong Chang¹,Xiang Yi¹,Shi Yanbo¹,Zhang Chennan¹,Yuan Aihua¹^ORCID,Zheng Shaojun¹^ORCID,Li Zhao-Yang²^ORCID,Zhang Yi-Quan³^ORCID,Yang Yong⁴,Chen Lei¹^ORCID

Affiliation:

1. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212100, PR China

2. School of Materials Science and Engineering, Nankai University, Tianjin 300350, PR China

3. Jiangsu Key Laboratory for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, PR China

4. College of Mechanical Engineering, Suzhou University of Science and Technology, Suzhou 215009, PR China

Abstract

Two air-stable eight-coordinate mononuclear Dy(iii) SMMs with a triangular dodecahedron exhibit high energy barriers of 444 K and 478 K and magnetic hysteresis temperatures of up to 8 K, which is attributed to one strong and short Dy–O bond.

Funder

National Natural Science Foundation of China

Six Talent Peaks Project in Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT01318A

Reference69 articles.

1. Magnetic bistability in a metal-ion cluster

2. High-spin molecules: [Mn12O12(O2CR)16(H2O)4]