Spirocyclic, macrocyclic and ladder complexes of coinage metals and mercury with dichalcogeno P2N2-supported anions
Author:
Affiliation:
1. School of Chemistry
2. University of St Andrews
3. St Andrews KY16 9ST
4. UK
5. Department of Chemistry
6. University of Calgary
7. Calgary
8. T2N 1N4 Canada
Abstract
Reactions of the dianions [tBuN(E)P(μ-NtBu)]22− (E = Se,S) with M(i) reagents (M = Ag, Au) or HgCl2 produce complexes of [tBu(H)N(E)P(μ-NtBu)2P(E)NtBu]− with spirocyclic, macrocyclic or ladder structures.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00159E
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