Fixation of atmospheric CO2 as C1-feedstock by nickel(ii) complexes

Author:

Muthuramalingam Sethuraman12345ORCID,Velusamy Marappan6785ORCID,Mayilmurugan Ramasamy12345ORCID

Affiliation:

1. Bioinorganic Chemistry Laboratory/Physical Chemistry

2. School of Chemistry

3. Madurai Kamaraj University

4. Madurai-625021

5. India

6. Department of Chemistry

7. North Eastern Hill University

8. Shillong 793022

Abstract

The Ni(ii) complexes of diazepane-based N3-ligands with a cis-β configuration showed the conversion of atmospheric or pure CO2 into cyclic carbonates under 1 atm pressure via a CO2-bound nickel(ii) intermediate.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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