Li+/H+ exchange of Li7La3Zr2O12 single and polycrystals investigated by quantitative LIBS depth profiling

Author:

Smetaczek Stefan1ORCID,Limbeck Andreas1ORCID,Zeller Veronika1ORCID,Ring Joseph1ORCID,Ganschow Steffen2ORCID,Rettenwander Daniel34ORCID,Fleig Jürgen1ORCID

Affiliation:

1. Institute of Chemical Technologies and Analytics, TU Wien, Vienna, Austria

2. Leibniz-Institut für Kristallzüchtung, Berlin, Germany

3. Department of Material Science and Engineering, NTNU Norwegian University of Science and Technology, Trondheim, Norway

4. International Christian Doppler Laboratory for Solid-State Batteries, NTNU Norwegian University of Science and Technology, Trondheim, Norway

Abstract

Pronounced Li+/H+ exchange of doped Li7La3Zr2O12 (LLZO) takes place in hot water. LIBS and ICP-OES analysis reveal the importance of grain boundaries in this ion exchange process.

Funder

Austrian Science Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

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