Modulating the reaction pathway of phenyl diazonium ions using host–guest complexation with cucurbit[7]uril-Reference-Cited by-同舟云学术

Modulating the reaction pathway of phenyl diazonium ions using host–guest complexation with cucurbit[7]uril

Published:2022 Issue:22 Volume:58 Page:3617-3620
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Moorthy Suresh¹,Castillo Bonillo Alvaro¹²,Lambert Hugues¹²^ORCID,Kalenius Elina³^ORCID,Lee Tung-Chun¹²^ORCID

Affiliation:

1. Institute for Materials Discovery, University College London (UCL), London WC1H 0AJ, UK

2. Department of Chemistry, University College London (UCL), London WC1H 0AJ, UK

3. Department of Chemistry, Nanoscience Center, University of Jyväskylä, Jyväskylä, Finland

Abstract

Encapsulation of a phenyl diazonium ion inside cucurbit[7]uril can effectively inhibit its reaction with water molecules while preserving its reactivity in diazo coupling reactions.

Funder

Engineering and Physical Sciences Research Council

Leverhulme Trust

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC06982A

Reference23 articles.

1. Synthesis of azobenzenes: the coloured pieces of molecular materials

2. Immobilized azobenzenes for the construction of photoresponsive materials

3. Ab Initio Study of the SN1Ar and SN2Ar Reactions of Benzenediazonium Ion with Water. On the Conception of “Unimolecular Dediazoniation” in Solvolysis Reactions

4. Cucurbituril-Based Molecular Recognition

5. New Cucurbituril Homologues: Syntheses, Isolation, Characterization, and X-ray Crystal Structures of Cucurbit[n]uril (n = 5, 7, and 8)

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