Revisiting the Mukaiyama-type epoxidation for the conversion of styrene into styrene carbonate in the presence of O2 and CO2

Author:

Balas Matthieu12,Mayoufi Asma1,Villanneau Richard2ORCID,Launay Franck1ORCID

Affiliation:

1. Sorbonne Université, CNRS, Campus Pierre et Marie Curie, Laboratoire de Réactivité de Surface, CNRS UMR 7197, 4 Place Jussieu, F-75005 Paris, France

2. Sorbonne Université, CNRS, Campus Pierre et Marie Curie, Institut Parisien de Chimie Moléculaire, CNRS UMR 8232, 4 Place Jussieu, F-75005 Paris, France

Abstract

Alkene epoxidation using the Mukaiyama process involving O2 and a sacrificial aldehyde, as the first step of the global alkene oxidative carboxylation, does not necessarily require a metal catalyst.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Sorbonne Université

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Reference50 articles.

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2. R. C.Allen , in: Bioluminescence and Chemiluminescence, Progress and Current Applications , ed. P. E. Stanley and L. J. Kricka , World Scientific , 2002 , pp. 223–232

3. I.Fleming , Frontier orbitals and organic chemical reactions , Chichester: John Wiley & Sons , 1978

4. THE PHYSICS, CHEMISTRY, AND BIOLOGY, OF SINGLET MOLECULAR OXYGEN

5. N. N.Greenwood and A.Earnshaw , Chemistry of the Elements , 3rd edn, 1986 , Pergamon Press , pp. 713–726

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