Synthesis, characterization and thermal behaviour of solid phases in the quasi-ternary system Mg(SCN)2–H2O

Synthesis, characterization and thermal behaviour of solid phases in the quasi-ternary system Mg(SCN)2–H2O–THF

Published:2021 Issue:20 Volume:50 Page:6949-6961
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Joos Markus¹²³,Conrad Maurice⁴⁵²³,Merkle Rotraut¹²³^ORCID,Schleid Thomas⁴⁵²³,Maier Joachim¹²³,Dinnebier Robert E.¹²³^ORCID,Bette Sebastian¹²³⁴⁵^ORCID

Affiliation:

1. Max Planck Institute for Solid State Research

2. 70569 Stuttgart

3. Germany

4. Institut für Anorganische Chemie

5. University of Stuttgart

Abstract

Mg(SCN)₂·4H₂O can be converted into Mg(SCN)₂·(4 − x)H₂O·xTHF compounds with x = 2 and 4 by multiple recrystallization in THF. Heating of Mg(SCN)₂·4THF leads to anisotropic lattice expansion, growing THF-disorder and eventually to Mg(SCN)₂·2THF.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00469G

Reference61 articles.

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