Effect of the electronic structure on the robustness of ruthenium(ii) bis-phenanthroline compounds for photodissociation of the co-ligand: synthesis, structural characterization, and density functional theory study-Reference-Cited by-同舟云学术

Effect of the electronic structure on the robustness of ruthenium(ii) bis-phenanthroline compounds for photodissociation of the co-ligand: synthesis, structural characterization, and density functional theory study

Published:2021 Issue:12 Volume:45 Page:5437-5451
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Deshpande Megha S.¹²³⁴^ORCID,Morajkar Sudesh M.¹²³⁴,Srinivasan Bikshandarkoil R.¹²³⁴,Ahirwar Mini Bharati⁵⁶⁷⁴,Deshmukh Milind M.⁵⁶⁷⁴^ORCID

Affiliation:

1. School of Chemical Sciences

2. Goa University

3. Goa 403206

4. India

5. Department of Chemistry

6. Dr Harisingh Gour Vishwavidyalaya (A Central University)

7. Sagar

Abstract

Photodissociation of co-ligand in cis-[Ru(phen)₂(L)₂](PF₆)₂ (phen = 1,10-phenanthroline, L = isoquinoline 1; phthalazine 2), upon blue light irradiation was investigated via both experimental and DFT studies.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D0NJ05921H

Reference80 articles.

1. Ligand photodissociation in Ru(ii)–1,4,7-triazacyclononane complexes enhances water oxidation and enables electrochemical generation of surface active species

2. Chemical and photochemical water oxidation catalyzed by novel ruthenium complexes comprising a negatively charged NCNHCO ligand

3. Solid-State Light-Emitting Devices Based on the Tris-Chelated Ruthenium(II) Complex. 4. High-Efficiency Light-Emitting Devices Based on Derivatives of the Tris(2,2‘-bipyridyl) Ruthenium(II) Complex

4. Application of d6 transition metal complexes in fluorescence cell imaging

5. Ruthenium(ii) polypyridyl complexes and DNA—from structural probes to cellular imaging and therapeutics

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