Pressure-and temperature induced phase transitions, piezochromism, NLC behaviour and pressure controlled Jahn–Teller switching in a Cu-based framework

Author:

McMonagle Charles J.12345,Comar Priyanka12345,Nichol Gary S.12345ORCID,Allan David R.6785ORCID,González Jesús910111213,Barreda-Argüeso José A.910111213ORCID,Rodríguez Fernando910111213,Valiente Rafael1415161317ORCID,Turner Gemma F.18192021,Brechin Euan K.12345ORCID,Moggach Stephen A.18192021ORCID

Affiliation:

1. School of Chemistry and Centre for Science at Extreme Conditions

2. The University of Edinburgh

3. King's Buildings

4. Edinburgh

5. UK

6. Diamond Light Source

7. Harwell Campus

8. Didcot

9. MALTA Team

10. CITIMAC

11. Facultad de Ciencias

12. University of Cantabria

13. 39005 Santander

14. Applied Physics Dept

15. Facultad de Cienicas

16. University of Cantabria – IDIVAL

17. Spain

18. School of Molecular Sciences and Centre for Microscopy, Characterisation and Analysis

19. University of Western Australia

20. Perth

21. Australia

Abstract

In situ high-pressure single-crystal diffraction and spectroscopic techniques have been used to study a previously unreported Cu-framework bis[1-(4-pyridyl)butane-1,3-dione]copper(ii) (CuPyr-I).

Funder

Engineering and Physical Sciences Research Council

Ministerio de Economía, Industria y Competitividad, Gobierno de España

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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