Reducing lifetime in Cu(i) complexes with thermally activated delayed fluorescence and phosphorescence promoted by chalcogenolate

Reducing lifetime in Cu(i) complexes with thermally activated delayed fluorescence and phosphorescence promoted by chalcogenolate–diimine ligands

Published:2020 Issue:41 Volume:8 Page:14595-14604
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Farias Giliandro¹²³⁴,Salla Cristian A. M.⁵²³⁴,S. Heying Renata¹²³⁴,Bortoluzzi Adailton J.¹²³⁴,Curcio Sergio F.⁵⁶⁷⁴,Cazati Thiago⁵⁶⁷⁴,dos Santos Paloma L.⁵⁸⁹¹⁰¹¹,Monkman Andrew P.⁵⁸⁹¹⁰¹¹^ORCID,Souza Bernardo de¹²³⁴,Bechtold Ivan H.⁵²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Universidade Federal de Santa Catarina

3. Florianópolis 88040-900

4. Brazil

5. Department of Physics

6. Universidade Federal de Ouro Preto

7. Ouro Preto 35400-000

8. Durham University

9. South Road

10. Durham

11. UK

Abstract

Cu(i) complexes without the expected heavy atom effect to enhance the spin–orbit coupling matrix elements, but with reduced photoluminescence lifetime.

Funder

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Financiadora de Estudos e Projetos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

Fundação de Amparo à Pesquisa e Inovação do Estado de Santa Catarina

Instituto Nacional de Ciência e Tecnologia em Eletrônica Orgânica

Universidade Federal de Ouro Preto

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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