Reversible redox reactions in metal-supported porphyrin: the role of spin and oxidation state-Reference-Cited by-同舟云学术

Reversible redox reactions in metal-supported porphyrin: the role of spin and oxidation state

Published:2021 Issue:37 Volume:9 Page:12559-12565
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Cojocariu Iulia¹^ORCID,Carlotto Silvia²³^ORCID,Zamborlini Giovanni¹^ORCID,Jugovac Matteo¹^ORCID,Schio Luca⁴^ORCID,Floreano Luca⁴^ORCID,Casarin Maurizio²^ORCID,Feyer Vitaliy¹⁵^ORCID,Schneider Claus Michael¹⁵

Affiliation:

1. Peter Grünberg Institute (PGI-6), Forschungszentrum Jülich GmbH, 52428 Jülich, Germany

2. Dipartimento di Scienze Chimiche, Università degli Studi di Padova, via F. Marzolo 1, 35131 Padova, Italy

3. Institute of Condensed Matter Chemistry and Technologies for Energy (ICMATE), National Research Council (CNR), c/o Department of Chemistry, University of Padova, via F. Marzolo 1, 35131 Padova, Italy

4. CNR-IOM, Lab. TASC, s.s. 14 km 163,5, 34149 Trieste, Italy

5. Fakultät f Physik and Center for Nanointegration Duisburg-Essen (CENIDE), Universität Duisburg-Essen, D-47048 Duisburg, Germany

Abstract

The reduced Co(i) metal ion in the molecular array facilitates the formation of the cobalt–ligand chemical bond already at RT. We demonstrate that molecular reactivity goes beyond the sole presence of unpaired electrons in the valence shell.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/TC/D1TC02222A

Reference44 articles.

1. Surface chemistry of porphyrins and phthalocyanines

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5. Ammonia Coordination Introducing a Magnetic Moment in an On-Surface Low-Spin Porphyrin

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