Mild reductive rearrangement of oximes and oxime ethers to secondary amines with hydrosilanes catalyzed by B(C6F5)3-Reference-Cited by-同舟云学术

Mild reductive rearrangement of oximes and oxime ethers to secondary amines with hydrosilanes catalyzed by B(C6F5)3

Published:2021 Issue:13 Volume:8 Page:3280-3285
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Fang Huaquan¹²³⁴^ORCID,Wang Guoqiang¹²³⁴⁵^ORCID,Oestreich Martin¹²³⁴^ORCID

Affiliation:

1. Institut für Chemie

2. Technische Universität Berlin

3. 10623 Berlin

4. Germany

5. Institute of Theoretical and Computational Chemistry

Abstract

Oximes, its ether derivatives and the corresponding hydroxylamines rearrange to secondary amines when reacted with PhSiH₃ and B(C₆F₅)₃ as catalyst. Computations suggest a reduction–rearrangement to be slightly favored over a Beckmann-type sequence.

Funder

Alexander von Humboldt-Stiftung

National Natural Science Foundation of China

Einstein Stiftung Berlin

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00251A

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