Formal hydrogenation of arynes with silyl Cβ–H bonds as an active hydride source-Reference-Cited by-同舟云学术

Formal hydrogenation of arynes with silyl Cβ–H bonds as an active hydride source

Published:2014 Issue:6 Volume:5 Page:2362-2367
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Mamidipalli Phani¹²³,Yun Sang Young¹²³,Wang Kung-Pern¹²³,Zhou Tao⁴⁵⁶,Xia Yuanzhi⁴⁵⁶,Lee Daesung¹²³

Affiliation:

1. Department of Chemistry

2. University of Illinois at Chicago

3. Chicago, USA

4. College of Chemistry and Materials Engineering

5. Wenzhou University

6. , P. R. China

Abstract

In stark contrast to the effective 1°, 2°, and 3° C–H bond insertion of alkyl groups tethered to arynes, the 2° and 3° C–H bonds on the β-carbon of silyl groups show high tendency for hydride transfer rather than C–H insertion, whereas the corresponding 1° C–H bonds exclusively undergo C–H insertion.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C3SC53478B

Reference62 articles.

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3. One Century of Aryne Chemistry

4. The Direct Acyl-Alkylation of Arynes

5. Synthesis of Xanthones, Thioxanthones, and Acridones by the Coupling of Arynes and Substituted Benzoates

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