Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones-Reference-Cited by-同舟云学术

Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones

Published:2015 Issue:12 Volume:6 Page:7319-7325
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang De¹²³⁴⁵,Wang Guo-Peng⁶⁷⁸⁹¹⁰,Sun Yao-Liang¹²³⁴⁵,Zhu Shou-Fei⁶⁷⁸⁹¹⁰,Wei Yin¹²³⁴⁵,Zhou Qi-Lin⁶⁷⁸⁹¹⁰,Shi Min¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Shanghai Institute of Organic Chemistry

3. Chinese Academy of Sciences

4. Shanghai 200032

5. P. R. China

6. State Key Laboratory and Institute of Element-Organic Chemistry

7. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)

8. Nankai University

9. Tianjin 300071

10. China

Abstract

The first regioselective catalytic asymmetric [3 + 2] cycloaddition of benzofuranone-derived olefins with allenoates and substituted allenoates has been developed in the presence of (R)-SITCP.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC03135D

Reference116 articles.

1. Phosphine-Catalyzed Cycloaddition of 2,3-Butadienoates or 2-Butynoates with Electron-Deficient Olefins. A Novel [3 + 2] Annulation Approach to Cyclopentenes

2. P. I. Dalko , Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Applications, Wiley-VCH, 2013, For reviews on phosphine-catalyzed reactions, see:

3. Reactions of Electron-Deficient Alkynes and Allenes under Phosphine Catalysis