Decomposition of lignin models enabled by copper-based photocatalysis under biphasic conditions

Author:

Bertin Cédric1,Cruché Corentin1,Chacón-Huete Franklin12ORCID,Forgione Pat2ORCID,Collins Shawn K.1ORCID

Affiliation:

1. Département de Chimie, Centre for Green Chemistry and Catalysis, Université de Montréal, 1375 Avenue Thérèse-Lavoie-Roux, Montréal, QC H2 V 0B3, Canada

2. Department of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke St W., Montreal, QC H4B 1R6, Canada

Abstract

A heteroleptic copper complex, Cu(bathocup)(XantPhos)BF4 promotes the fragmentation of lignin models of the β-O-4 linkage under aqueous biphasic reaction conditions using catalytic amounts of NABnH, a hydrogen atom donor.

Funder

Université de Montréal

Concordia University

Mitacs

Natural Sciences and Engineering Research Council of Canada

Fonds de Recherche du Québec - Nature et Technologies

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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