Selective oxidation of silanes into silanols with water using [MnBr(CO)<sub>5</sub>] as a precatalyst-Reference-Cited by-同舟云学术

Selective oxidation of silanes into silanols with water using [MnBr(CO)₅] as a precatalyst

Published:2023 Issue:1 Volume:14 Page:54-60
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Antico Emanuele¹²^ORCID,Leutzsch Markus³^ORCID,Wessel Niklas¹²^ORCID,Weyhermüller Thomas¹^ORCID,Werlé Christophe¹⁴^ORCID,Leitner Walter¹²^ORCID

Affiliation:

1. Max Planck Institute for Chemical Energy Conversion, Stiftstr. 34–36, 45470 Mülheim an der Ruhr, Germany

2. Institut für Technische und Makromolekulare Chemie (ITMC), RWTH Aachen University, Worringer Weg 2, 52074 Aachen, Germany

3. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany

4. Ruhr University Bochum, Universitätsstr. 150, 44801 Bochum, Germany

Abstract

This study presents the use of MnBr(CO)5 for the selective conversion of silanes to silanols with water as an oxidant generating valuable hydrogen as the only by-product.

Funder

Max-Planck-Gesellschaft

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC05959B

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