Molecular transport and water condensation inside mesopores with wettability step gradients

Author:

Despot Laura1ORCID,Hinduja Chirag2,Lehn Robert1,Mikolei Joanna1,Richter Timo3,Köbschall Kilian3,Stanzel Mathias1,Berger Rüdiger2ORCID,Hussong Jeanette3ORCID,Ceolín Marcelo4,Andrieu-Brunsen Annette1

Affiliation:

1. Ernst-Berl-Institut für Technische und Makromolekulare Chemie, Technische Universität Darmstadt, 64289 Darmstadt, Germany

2. Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany

3. Institut für Strömungslehre und Aerodynamik, Technische Universität Darmstadt, Peter-Grünberg-Straße 10, 64289 Darmstadt, Germany

4. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas, Universidad Nacional de La Plata and CONICET, Diag. 113 y 64 (1900), La Plata, Argentina

Abstract

Mesoporous silica films with adjustable wettability and wettability step gradients are fabricated. An influence of the upper hydrophobic layer thickness on water vapor adsorption and condensation as well as on mass and fluid transport is observed.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Engineering,General Materials Science,General Chemistry,Atomic and Molecular Physics, and Optics,Bioengineering

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