Enantioselective synthesis of polycyclic pyrrole derivatives by iridium-catalyzed asymmetric allylic dearomatization and ring-expansive migration reactions-Reference-Cited by-同舟云学术

Enantioselective synthesis of polycyclic pyrrole derivatives by iridium-catalyzed asymmetric allylic dearomatization and ring-expansive migration reactions

Published:2021 Issue:44 Volume:57 Page:5390-5393
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Huang Lin¹²³⁴⁵,Xie Jia-Hao¹²³⁴⁵,Cai Yue¹²³⁴⁵,Zheng Chao¹²³⁴⁵^ORCID,Hou Xue-Long¹²³⁴⁵,Dai Li-Xin¹²³⁴⁵,You Shu-Li¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Organometallic Chemistry

2. Center for Excellence in Molecular Synthesis

3. Shanghai Institute of Organic Chemistry

4. University of Chinese Academy of Sciences

5. Chinese Academy of Sciences

Abstract

A cascade Ir-catalyzed asymmetric allylic daromatization/ring-expansive migration reaction affords tetrahydropyrrolo[1,2-c]pyrimidine derivatives in good yields with high enantioselectivity.

Funder

Science and Technology Commission of Shanghai Municipality

Youth Innovation Promotion Association of the Chinese Academy of Sciences

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01929E

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