Polymorphism and benzene solvent controlled stimuli responsive reversible fluorescence switching in triphenylphosphoniumfluorenylide crystals

Author:

Hariharan P. S.12345,Mariyatra M. Baby1675,Mothi E. M.8910115ORCID,Neels Antonia1213141516,Rosair Georgina1718192021,Anthony Savarimuthu Philip12345ORCID

Affiliation:

1. Department of Chemistry

2. School of Chemical & Biotechnology

3. SASTRA University

4. Thanjavur-613401

5. India

6. St. Xavier's College

7. Palayamkottai-627002

8. Centre for Scientific and Applied Research

9. PSN College of Engineering and Technology

10. Melathediyoor

11. Tirunelveli-627152

12. Center for X-ray Analytics

13. Empa – Swiss Federal Laboratories for Materials Science and Technology

14. Überlandstrasse 129

15. 8600 Dübendorf

16. Switzerland

17. Institute of Chemical Sciences

18. School of Engineering & Physical Sciences

19. Heriot-Watt University

20. Edinburgh

21. UK

Abstract

Triphenylphosphoniumfluorenylide (TPPFY), a fluorescent fluorene attached molecule, showed polymorphism, benzene solvent induced aggregation enhanced emission (AEE) and external stimuli responsive on–off fluorescence switching.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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