Difluoro- and trifluoro diazoalkanes – complementary approaches in batch and flow and their application in cycloaddition reactions-Reference-Cited by-同舟云学术

Difluoro- and trifluoro diazoalkanes – complementary approaches in batch and flow and their application in cycloaddition reactions

Published:2017 Issue:4 Volume:19 Page:905-909
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Hock Katharina J.¹²³⁴,Mertens Lucas¹²³⁴,Metze Friederike K.¹²³⁴,Schmittmann Clemens¹²³⁴,Koenigs Rene M.¹²³⁴^ORCID

Affiliation:

1. RWTH Aachen University

2. Institute of Organic Chemistry

3. D-52074 Aachen

4. Germany

Abstract

Fluorinated diazoalkanes can be obtained in either batch or continuous-flow reactions, depending on the substitution pattern. These diazo compounds were applied in dipolar cycloadditions yielding sulfonated heterocycles.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/GC/C6GC03187K

Reference55 articles.

1. Fluorinated diazoalkanes – a versatile class of reagents for the synthesis of fluorinated compounds

2. Preparation of trifluoromethyl-pyrazoles and -pyrazolines by the reaction of 2,2,2-trifluorodiazoethane with carbon-carbon multiple bonds

3. 366. Carbene chemistry. Part I. Reactions of fluoroalkyldiazo-compounds

4. 2,2,2-Trifluoroethylamine and 2,2,2-Trifluorodiazoethane

5. Iron-Catalyzed Cyclopropanation with Trifluoroethylamine Hydrochloride and Olefins in Aqueous Media: In Situ Generation of Trifluoromethyl Diazomethane

Cited by 72 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Regioselective Synthesis of Multisubstituted Fluoropyrazoles via Silver‐Catalyzed One‐Pot Cyclization Reaction of Diazo Reagents with Fluoronitroalkenes;Advanced Synthesis & Catalysis;2024-06-17

2. Trifluoroacetaldehyde N-tosylhydrazone in [3+2] cycloaddition reaction for the synthesis of 5-(trifluoromethyl)pyrazolines;Russian Chemical Bulletin;2024-04

3. Copper-catalyzed multicomponent reaction of β-trifluoromethyl β-diazo esters enabling the synthesis of β-trifluoromethyl N,N-diacyl-β-amino esters;Beilstein Journal of Organic Chemistry;2024-02-02

4. Photoinduced [3+2] Cycloaddition of Alkyl–Acceptor Diazoalkanes: Diversity-Oriented Synthesis of Pyrazolines Containing a Quaternary Center;Organic Letters;2024-01-26

5. Aza-Wittig reaction of (β-diazo-α,α-difluoroethyl)phosphonates with aldehydes for the synthesis of difluoromethylphosphonate-containing arylidene hydrazones;Journal of Fluorine Chemistry;2024-01