The role of O(1D) in the oxidation mechanism of ethylene by iodosobenzene and other hypervalent molecules

Author:

Khan Shahriar N.1234ORCID,Miliordos Evangelos1234ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Auburn University

3. Auburn

4. USA

Abstract

Terminal iodine–oxygen bonds are described as PhI → O(1D) dative bonds explaining the oxidation properties of iodosobenzene or other “hypervalent” species.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference20 articles.

1. IUPAC , Compendium of Chemical Terminology, (the “Gold Book”), Compiled by A. D. McNaught and A. Wilkinson, Blackwell Scientific Publications, Oxford, 2nd edn, 1997

2. XML on-line corrected version: http://goldbook.iupac.org, 2006, created by M. Nic, J. Jirat and B. Kosata; updates compiled by A. Jenkins. ISBN 0-9678550-9-8. https://doi.org/10.1351/goldbook

3. K. W. Whitten , R. E.Davis, L.Peck and G. C.Stanley, Chemistry, Cengage learning, USA, 10th edn, 2014

4. R. H. Petrucci , F. G.Herring, J. D.Madura and C.Bissonnette, General Chemistry, Pearson Canada Inc., Toronto, 10th edn, 2011

5. The octet rule and hypervalence: two misunderstood concepts

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