Site-selective halogenation on meso-mesityl substituents of 10,20-dimesityl-5,15-diazaporphyrins with an AuX3/AgOTf combination
Author:
Affiliation:
1. Department of Molecular and Macromolecular Chemistry
2. Graduate School of Engineering
3. Nagoya University
4. Nagoya
5. Japan
Abstract
An AuBr3/AgOTf combination achieves site-selective bromination on the mesityl substituents of 10,20-dimesityl-5,15-diazaporphyrins.
Funder
Japan Society for the Promotion of Science
Sumitomo Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02727H
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4. Regioselective Borylation of Porphyrins by CH Bond Activation under Iridium Catalysis to Afford Useful Building Blocks for Porphyrin Assemblies
5. Highly selective Ir-catalyzed direct sixfold borylation of peripheral aromatic substituents on hexakisaryl-substituted [28]hexaphyrin(1.1.1.1.1.1)
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