The effects of MTG catalysis on methanol mobility in ZSM-5

Author:

Matam S. K.12345ORCID,O'Malley A. J.45673ORCID,Catlow C. R. A.45673,Suwardiyanto Suwardiyanto891011,Collier P.12133,Hawkins A. P.1415163ORCID,Zachariou A.1415163ORCID,Lennon D.1415163,Silverwood I.176183ORCID,Parker S. F.45673ORCID,Howe R. F.8193ORCID

Affiliation:

1. Department of Chemistry

2. University College London

3. UK

4. UK Catalysis Hub

5. Research Complex at Harwell

6. STFC Rutherford Appleton Laboratory

7. Chilton

8. Chemistry Department

9. University of Jember

10. Jember

11. 68121 Indonesia

12. Johnson-Matthey Technology Centre

13. Sonning Common

14. School of Chemistry

15. University of Glasgow

16. Glasgow G12 8QQ

17. ISIS Facility

18. Chilton OX11 0QX

19. University of Aberdeen

Abstract

QENS shows that methanol is immobile in a fresh ZSM-5 catalyst and one used for methanol conversion at 623 K, but undergoes isotropic rotation within the mesopores generated in a catalyst used for methanol conversion at 673 K.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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