DPDS–DPS in situ transformation at room temperature via a 1,2-nucleophilic addition mechanism-Reference-Cited by-同舟云学术

DPDS–DPS in situ transformation at room temperature via a 1,2-nucleophilic addition mechanism

Published:2014 Issue:36 Volume:16 Page:8322-8326
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

De la Pinta Noelia¹²³⁴,Caballero Ana B.⁵⁶⁷⁸,Madariaga Gotzon¹²³⁴,Ezpeleta José M.⁵⁹³¹⁰,Rodriguez-Dieguez Antonio⁵⁶⁷⁸,Salas Juan M.⁵⁶⁷⁸,Cortés Roberto⁵²³⁴

Affiliation:

1. Dpto. de Física de la Materia Condensada

2. Facultad de Ciencia y Tecnología

3. Universidad del País Vasco

4. 48080 Bilbao, Spain

5. Dpto. de Química Inorgánica

6. Facultad de Ciencias

7. Universidad de Granada

8. 18071 Granada, Spain

9. Facultad de Farmacia

10. 01080 Vitoria-Gasteiz, Spain

Abstract

A cleavage–reorganization reaction at room temperature has been detected in three metal organic coordination compounds synthesized from a DPDS [di(4-pyridyl)disulphide] ligand: Mn(NCS)₂(DPS)₄ (1), [Fe(NCS)₂(DPS)₂]·2H₂O (2) and Zn(NCO)₂(DPS) (3), [DPS = di(4-pyridyl)sulphide].

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CE/C4CE00781F

Reference38 articles.

1. Synthesis and Crystallographic Characterization of Low-Dimensional and Porous Coordination Compounds Capable of Supramolecular Aromatic Interaction Using the 4,4‘-Azobis(pyridine) Ligand

2. Construction of Pyridinethiolate-Bridged 2D and 3D Coordination Networks of d10 Metal Halides via Solvothermal in Situ Disulfide Cleavage Reactions

3. Transition metal coordination frameworks with bridges of 1,2-bis(4-pyridyl)ethane-N,N′-dioxide incorporating anions of different size

4. Temperature-Dependent Guest-Driven Single-Crystal-to-Single-Crystal Ligand Exchange in a Two-Fold Interpenetrated CdIIGrid Network

5. Structural, Spectroscopic, and Magnetic Characterization of the Coordination Polymers [MII(NCS)2(bpe)2]·3H2O·2C2H6SO [M = Co, Ni; bpe = 1,2-Bis(4-pyridyl)ethylene]. Two Interpenetrated Porous Networks

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