Enantiodivergent asymmetric catalysis with the tropos BIPHEP ligand and a proline derivative as chiral selector
Author:
Affiliation:
1. Institut für Technische und Makromolekulare Chemie
2. RWTH Aachen University
3. 52074 Aachen
4. Germany
Abstract
Enantiomer on demand: tropos ligand BIPHEP and chiral selector (S)-proline methyl ester allow enantiodivergent Rh-catalysed hydrogenation and asymmetric styrene hydroboration.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC03465E
Reference38 articles.
1. E. N. Jacobsen , A.Pfaltz and H.Yamamoto, Comprehensive Asymmetric Catalysis, Springer, Berlin, 1999
2. Enantioselective catalysis with transition metal complexes
3. Centenary Lecture. Chemical multiplication of chirality: science and applications
4. TroposorAtropos? That is the Question!
5. Asymmetric Catalysis by Architectural and Functional Molecular Engineering: Practical Chemo- and Stereoselective Hydrogenation of Ketones
Cited by 21 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Switchable supramolecular helices for asymmetric stereodivergent catalysis;Nature Communications;2024-05-15
2. Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis;Chemical Reviews;2024-04-25
3. Controlling the Enantioselectivity in an Adaptable Ligand by Biomimetic Intramolecular Interlocking;The Journal of Organic Chemistry;2022-08-08
4. Synthesis of Stereochemically Flexible Cyclic Biphenylbisphosphinite Ligands: Control of the Dynamics and Selectivity;Helvetica Chimica Acta;2021-11-10
5. Structural and catalytic properties of the [Ni(BIPHEP)X2] complexes, BIPHEP = 2,2-diphenylphosphino-1,1-biphenyl; X = Cl, Br;Inorganica Chimica Acta;2021-07
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3