Luminescent gold–thallium derivatives with a pyridine-containing 12-membered aza-thioether macrocycle-Reference-Cited by-同舟云学术

Luminescent gold–thallium derivatives with a pyridine-containing 12-membered aza-thioether macrocycle

Published:2021 Issue:28 Volume:50 Page:9709-9718
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Caddeo Francesco¹²³⁴⁵,Fernández-Moreira Vanesa¹²³⁴⁵^ORCID,Arca Massimiliano⁶⁷⁸⁹^ORCID,Pintus Anna⁶⁷⁸⁹,Laguna Antonio¹²³⁴⁵,Lippolis Vito⁶⁷⁸⁹^ORCID,Gimeno M. Concepción¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química Inorgánica

2. Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

3. CSIC-Universidad de Zaragoza

4. 50009 Zaragoza

5. Spain

6. Dipartimento di Scienze Chimiche e Geologiche

7. Università degli Studi di Cagliari

8. 09042 Monserrato

9. Italy

Abstract

The heterometallic Tl^I/Au^I complex {[Au(C₆F₅)₂Tl]₂(L)}_n has an unprecedented polymeric structural motif with a metallic pseudo-rhombic Au₂Tl₂ core that repeats itself to form zig-zag polymers and shows a thermochromic behaviour.

Funder

Ministerio de Ciencia e Innovación

Gobierno de Aragón

Fondazione di Sardegna

Regione Autonoma della Sardegna

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01599K

Reference67 articles.