Soft phonon modes from off-center Ge atoms lead to ultralow thermal conductivity and superior thermoelectric performance in n-type PbSe–GeSe

Author:

Luo Zhong-Zhen12345ORCID,Hao Shiqiang6578,Zhang Xiaomi6578ORCID,Hua Xia6578ORCID,Cai Songting45786,Tan Gangjian4578ORCID,Bailey Trevor P.910118ORCID,Ma Runchu910118,Uher Ctirad910118ORCID,Wolverton Chris6578ORCID,Dravid Vinayak P.6578ORCID,Yan Qingyu123ORCID,Kanatzidis Mercouri G.4578ORCID

Affiliation:

1. School of Materials Science and Engineering

2. Nanyang Technological University

3. Singapore

4. Department of Chemistry

5. Northwestern University

6. Department of Materials Science and Engineering

7. Evanston

8. USA

9. Department of Physics

10. University of Michigan

11. Ann Arbor

Abstract

The off-centered Ge leads to the ultralow lattice thermal conductivity and record high average ZT for n-type PbSe.

Funder

National Natural Science Foundation of China

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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