Reduction-induced CO dissociation by a [Mn(bpy)(CO)4][SbF6] complex and its relevance in electrocatalytic CO2reduction-Reference-Cited by-同舟云学术

Reduction-induced CO dissociation by a [Mn(bpy)(CO)4][SbF6] complex and its relevance in electrocatalytic CO2reduction

Published:2020 Issue:3 Volume:49 Page:891-900
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kuo Hsin-Ya¹²³⁴^ORCID,Tignor Steven E.¹²³⁴,Lee Tia S.¹²³⁴,Ni Danrui¹²³⁴,Park James Eujin¹²³⁴,Scholes Gregory D.¹²³⁴^ORCID,Bocarsly Andrew B.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Princeton University

3. Princeton

4. USA

Abstract

[Mn(bpy)(CO)₄] is isolated, characterized, and demonstrated to be an on-cycle catalytic intermediate in the [MnX(bpy)(CO)₃]-catalyzed electroreduction of CO₂to CO.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04150H

Reference37 articles.

1. Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes

2. Mechanistic aspects of CO2 reduction catalysis with manganese-based molecular catalysts

3. Molecular polypyridine-based metal complexes as catalysts for the reduction of CO2