A rational quest for selectivity through precise ligand-positioning in tandem DNA-catalysed Friedel–Crafts alkylation/asymmetric protonation-Reference-Cited by-同舟云学术

A rational quest for selectivity through precise ligand-positioning in tandem DNA-catalysed Friedel–Crafts alkylation/asymmetric protonation

Published:2019 Issue:10 Volume:10 Page:2875-2881
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mansot Justine¹²³⁴⁵,Aubert Sidonie⁶⁷⁸⁹,Duchemin Nicolas⁶⁷⁸⁹,Vasseur Jean-Jacques¹²³⁴⁵^ORCID,Arseniyadis Stellios⁶⁷⁸⁹^ORCID,Smietana Michael¹²³⁴⁵^ORCID

Affiliation:

1. Institut des Biomolécules Max Mousseron

2. CNRS

3. Université de Montpellier

4. ENSCM

5. 34095 Montpellier

6. School of Biological and Chemical Sciences

7. Queen Mary University of London

8. London E1 4NS

9. UK

Abstract

We report here a highly selective copper(II)-catalysed asymmetric Friedel–Crafts conjugate addition/enantioselective protonation, which owes to a careful positioning of a bipyridine ligand within a DNA framework.

Funder

Agence Nationale de la Recherche

Queen Mary University of London

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC05543B

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1. Artificial Metalloenzymes: Reaction Scope and Optimization Strategies

2. A decade of DNA-hybrid catalysis: from innovation to comprehension