Nickel-catalysed enantioselective reaction of secondary phosphine oxides and activated vinylcyclopropanes-Reference-Cited by-同舟云学术

Nickel-catalysed enantioselective reaction of secondary phosphine oxides and activated vinylcyclopropanes

Published:2023 Issue:15 Volume:21 Page:3096-3100
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Huang Zhuo¹,Liu Xu-Teng¹,Cui Ranran¹,Zhang Qing-Wei¹^ORCID

Affiliation:

1. Key Laboratory of Precision and Intelligent Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei 230026, People's Republic of China

Abstract

A nickel-catalyzed asymmetric allylation of racemic secondary phosphine oxides with racemic vinylcyclopropanes was described. The Tertiary phosphine oxide products were obtained with up to 91% yield and 92% ee.

Funder

National Natural Science Foundation of China

University of Science and Technology of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB00389B

Reference71 articles.

1. Q. L.Zhou , in Privileged Chiral Ligands and Catalysts , ed. W. Zhang and X. Zhang , Wiley-VCH, New York , 2011 , p. 55

2. New Chiral Phosphorus Ligands for Enantioselective Hydrogenation