Spectroscopic and electrochemical characterization of a Pr4+ imidophosphorane complex and the redox chemistry of Nd3+ and Dy3+ complexes-Reference-Cited by-同舟云学术

Spectroscopic and electrochemical characterization of a Pr⁴⁺ imidophosphorane complex and the redox chemistry of Nd³⁺ and Dy³⁺ complexes

Published:2022 Issue:17 Volume:51 Page:6696-6706
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rice Natalie T.¹^ORCID,Popov Ivan A.²³,Carlson Rebecca K.²,Greer Samuel M.⁴,Boggiano Andrew C.¹^ORCID,Stein Benjamin W.⁴^ORCID,Bacsa John¹,Batista Enrique R.²^ORCID,Yang Ping²^ORCID,La Pierre Henry S.¹⁵^ORCID

Affiliation:

1. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, USA

2. Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

3. Department of Chemistry, The University of Akron, Akron, OH 44325-3601, USA

4. Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

5. Nuclear and Radiological Engineering and Medical Physics Program, School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, USA

Abstract

Tetravalent praseodymium in a homoleptic imidophosphorane complex is identified and characterized in solution via UV-vis-NIR, cyclic voltammetry, theoretical calculations, and X-band EPR.

Funder

Basic Energy Sciences

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00758D

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