Pulsed electron–electron double resonance spectroscopy between a high-spin Mn2+ ion and a nitroxide spin label
Author:
Affiliation:
1. Goethe University Frankfurt am Main
2. Institute of Physical and Theoretical Chemistry and Center for Biomolecular Magnetic Resonance
3. 60438 Frankfurt am Main
4. Germany
Abstract
PELDOR experiments on a Mn2+–nitroxide complex were performed. At 1.2 T the Mn2+–nitroxide distance was determined by probing both spins. PELDOR obtained at 6.4 T provided as well the orientation of the nitroxide with respect to the dipolar vector connecting the spins.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP05362A
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