Catalytic Au(i)/Au(iii) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles-Reference-Cited by-同舟云学术

Catalytic Au(i)/Au(iii) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles

Published:2019 Issue:30 Volume:10 Page:7183-7192
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rodriguez Jessica¹²³⁴^ORCID,Zeineddine Abdallah¹²³⁴,Sosa Carrizo E. Daiann⁵⁶⁷⁸⁴^ORCID,Miqueu Karinne⁵⁶⁷⁸⁴^ORCID,Saffon-Merceron Nathalie⁹³⁴,Amgoune Abderrahmane¹²³⁴,Bourissou Didier¹²³⁴^ORCID

Affiliation:

1. CNRS/Université Paul Sabatier

2. Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA, UMR 5069)

3. 31062 Toulouse Cedex 09

4. France

5. CNRS/UNIV PAU & PAYS ADOUR

6. Institut des Sciences Analytiques et de Physico-Chimie pour l’Environnement et les Matériaux

7. (IPREM UMR 5254)

8. 64053 Pau Cedex 09

9. Institut de Chimie de Toulouse (FR 2599)

Abstract

The ability of the MeDalphos ligand to trigger oxidative addition of iodoarenes preferentially electron-rich, to gold has been thoroughly studied and exploited to develop an efficient Au(i)/Au(iii)-catalysed C3-arylation of indoles.

Funder

Centre National de la Recherche Scientifique

Université de Toulouse

Fundación Ramón Areces

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01954E

Reference105 articles.