Synthesis of a 1-aza-2-phospha-acenaphthene complex profiting from coordination enabled chloromethane elimination

Author:

Biskup David1ORCID,Bergmann Tom1,Schnakenburg Gregor1ORCID,Gomila Rosa M.2ORCID,Frontera Antonio2ORCID,Streubel Rainer1ORCID

Affiliation:

1. Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Str. 1, 53121 Bonn, Germany

2. Department of Chemistry, Universitat de les Illes Balears, crts de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain

Abstract

The formation of an annulated P-heterocycle is described using a bond activation elimination sequence through intramolecular N→P interactions in peri-substituted naphthalene derivatives and through transition metal coordination.

Funder

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference38 articles.

1. R. H.Crabtree , The organometallic chemistry of the transition metals , Wiley , Hoboken, NJ , 5th edn, 2009

2. M.Peruzzini and L.Gonsalvi , Phosphorus compounds. Advanced tools in catalysis and material sciences , Springer , Dordrecht , 2011

3. N. N.Greenwood and A.Earnshaw , Chemistry of the elements , Elsevier-Butterworth-Heinemann , Amsterdam , 2nd edn, 1997

4. The Reactions of Phosphorus and Antimony Chlorides with Trimethylamine, Triethylamine and Trimethylphosphine1

5. Donor-Acceptor Complexes between Simple Phosphines. First Structural Data for an Almost Forgotten Class of Compounds

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