A rare olefin 1,1-carboboration reaction opens a synthetic pathway to an unusually structured frustrated Lewis pair-Reference-Cited by-同舟云学术

A rare olefin 1,1-carboboration reaction opens a synthetic pathway to an unusually structured frustrated Lewis pair

Published:2020 Issue:62 Volume:56 Page:8806-8809
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Chaohuang¹²³⁴,Daniliuc Constantin G.¹²³⁴^ORCID,Mück-Lichtenfeld Christian¹²³⁴^ORCID,Kehr Gerald¹²³⁴^ORCID,Erker Gerhard¹²³⁴^ORCID

Affiliation:

1. Organisch-Chemisches Institut

2. Westfälische Wilhelms-Universität Münster

3. 48149 Münster

4. Germany

Abstract

The bulky aryl(divinyl)phosphane reacts with Piers’ borane by a sequence involving a rare olefinic 1,1-carboboration to give the active phosphane/borane Lewis pair.

Funder

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC01255F

Reference62 articles.

1. Metallacyclopentadienes and related heterocycles via 1,1-organoboration of alkyn-1-ylmetal compounds

2. 1,1-Carboboration

3. 1,1‐Carboboration through Activation of Silicon–Carbon and Tin–Carbon Bonds

4. Theoretical study on the consecutive 1,2-hydroboration and 1,1-organoboration reactions of alkyn-1-yl(vinyl)silane with borane

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