Displacement of ethene from the decamethyltitanocene-ethene complex with internal alkynes, substituent-dependent alkyne-to-allene rearrangement, and the electronic transition relevant to the back-bonding interaction-Reference-Cited by-同舟云学术

Displacement of ethene from the decamethyltitanocene-ethene complex with internal alkynes, substituent-dependent alkyne-to-allene rearrangement, and the electronic transition relevant to the back-bonding interaction

Published:2015 Issue:16 Volume:44 Page:7276-7291
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pinkas Jiří¹²³⁴,Gyepes Róbert⁵⁶⁷⁸⁹,Císařová Ivana⁹¹⁰¹¹⁴,Kubišta Jiří¹²³⁴,Horáček Michal¹²³⁴,Mach Karel¹²³⁴

Affiliation:

1. J. Heyrovský Institute of Physical Chemistry

2. Academy of Sciences of the Czech Republic

3. 182 23 Prague 8

4. Czech Republic

5. J. Selye University

6. Faculty of Education

7. 945 01 Komárno

8. Slovak Republic

9. Department of Inorganic Chemistry

10. Charles University

11. 128 40 Prague 2

Abstract

Internal alkyne substituents control the first excitation energy of decamethyltitanocene-η²-alkyne complexes and isomerisation to η²-allene complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00351B

Reference65 articles.

1. Structure and reactivity of bis(pentamethylcyclopentadienyl)(ethylene)titanium(II), a simple olefin adduct of titanium

2. Structure and chemistry of bis(cyclopentadienyl)-MLn complexes

3. Titanacycles derived from reductive coupling of nitriles, alkynes, acetaldehyde, and carbon dioxide with bis(pentamethylcyclopentadienyl)(ethylene)titanium(II)

4. Ethene Complexes of Bulky Titanocenes, Their Thermolysis, and Their Reactivity toward 2-Butyne

Cited by 17 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Ca(II) and Yb(II) complexes featuring M(C≡C)₄ structural motif: enforced proximity or genuine η²‐bonding?;Chemistry – A European Journal;2024-01-10

2. Acetylene complexes of metallocenes of titanium, zirconium and hafnium. I. Synthesis, structure, and spectral characteristics;Coordination Chemistry Reviews;2023-10

3. Reactions of a Bis(pentalene)dititanium complex with alkenes; the molecular structure of the butadiene complex [Ti2(µ: η5,η5-Pn††)2(μ: η2,η2-s-trans-C4H6)] (Pn†† = 1,4-(Si Pr3)2-C8H4);Polyhedron;2022-01

4. Sunlight-induced dehydrogenation rearrangement of the dititanium complex [Ti(η5-C5HMe4)(μ-η1: η5-C5Me4)]2;Journal of Organometallic Chemistry;2021-02

5. Mechanistic insights into dehydrocoupling of amine boranes using dinuclear zirconocene complexes;Catalysis Science & Technology;2021