Simple access to β-trifluoromethyl-substituted ketones via copper-catalyzed ring-opening trifluoromethylation of substituted cyclopropanols-Reference-Cited by-同舟云学术

Simple access to β-trifluoromethyl-substituted ketones via copper-catalyzed ring-opening trifluoromethylation of substituted cyclopropanols

Published:2015 Issue:39 Volume:51 Page:8349-8352
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kananovich Dzmitry G.¹²³⁴,Konik Yulia A.⁵⁶⁷⁸,Zubrytski Dzmitry M.⁵⁶⁷⁸,Järving Ivar¹²³⁴,Lopp Margus¹²³⁴

Affiliation:

1. Department of Chemistry

2. Tallinn University of Technology

3. 12618 Tallinn

4. Estonia

5. Department of Organic Chemistry

6. Belarusian State University

7. Minsk

8. Belarus

Abstract

A variety of β-trifluoromethyl ketones have been easily prepared by CuCl-catalyzed ring-opening trifluoromethylation of cyclopropanols with Togni reagent.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC02386F

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3. Fluorine in medicinal chemistry

4. V. Prakash Reddy , Organofluorine Compounds in Biology and Medicine, Elsevier, Amsterdam, 2015

5. Asymmetric Fluorination, Trifluoromethylation, and Perfluoroalkylation Reactions

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