Total synthesis of dissectol A, using an enediolate-based Tsuji–Trost reaction-Reference-Cited by-同舟云学术

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Total synthesis of dissectol A, using an enediolate-based Tsuji–Trost reaction

Published:2024 Issue:27 Volume:15 Page:10541-10546
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Andringa Ruben L. H.¹,Marinus Nittert¹,Bunt Daan V.¹,Haiderer Elizabeth R.²,Abramovitch Robert B.²,Brown Christopher D.³^ORCID,Rhee Kyu Y.³,Witte Martin D.¹^ORCID,Minnaard Adriaan J.¹^ORCID

Affiliation:

1. Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG, Groningen, The Netherlands

2. Department of Microbiology, Genetics and Immunology, Michigan State University, East Lansing, MI, 48824, USA

3. Weill Cornell Medicine, Division of Infectious Diseases, 1315 York Avenue, Stitch Building, New York, NY10021, USA

Abstract

The densely functionalized terpene glycoside dissectol A has been prepared via site-selective oxidation and an intramolecular Tsuji–Trost allylic alkylation reaction with an enediolate as the nucleophile.

Funder

AgBioResearch, Michigan State University

National Institute of Allergy and Infectious Diseases

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01745E

Reference27 articles.

1. Dissectol A, An Unusual Monoterpene Glycoside fromIncarvillea dissectifoliola

2. VIRTUAL SCREENING OF MEDICINAL PLANT COMPOUNDS AGAINST DevR (A0R2V2) OF Mycobacterium tuberculosis USING MOLECULAR DOCKING STUDIES

3. Lignans, Monoterpenes and γ‐ Pyrone Derivatives from Patrinia scabiosifolia with Cytotoxic Activity against HCT‐116 Cells

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