Influence of the N–H functionality on activating O,N,N-titanium complexes and controlling polyethylene molecular weights and distributions-Reference-Cited by-同舟云学术

Influence of the N–H functionality on activating O,N,N-titanium complexes and controlling polyethylene molecular weights and distributions

Published:2024 Issue:2 Volume:11 Page:613-623
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Tian Jiliang¹,Gao Zhihao¹,Liu Yongxin¹,Braunstein Pierre²^ORCID,Liu Shaofeng¹^ORCID,Li Zhibo¹³^ORCID

Affiliation:

1. Key Laboratory of Biobased Polymer Materials, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China

2. Institut de Chimie (UMR 7177 CNRS), Université de Strasbourg, 4 rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France

3. College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

Abstract

Ti complexes supported by O,N,N-ligands show unprecedented activity in ethylene polymerization and produce polymers with unimodal/narrow or bimodal/broad distributions, depending upon amine-N substituents and catalyst pre-activation or not.

Funder

Higher Education Discipline Innovation Project

National Natural Science Foundation of China

Key Technology Research and Development Program of Shandong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QI/D3QI02128A

Reference62 articles.

1. From Multisite Polymerization Catalysis to Sustainable Materials and All-Polyolefin Composites

2. Polyolefin thermoplastic elastomers from polymerization catalysis: Advantages, pitfalls and future challenges

3. Effect of Molecular Structure on the Linear Viscoelastic Behavior of Polyethylene

4. Neutral Nickel(II) Catalysts: From Hyperbranched Oligomers to Nanocrystal-Based Materials

5. Ultrahigh molecular weight polyethylene: Catalysis, structure, properties, processing and applications

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