The insensitive cation effect on a single atom Ni catalyst allows selective electrochemical conversion of captured CO2 in universal media

Author:

Kim Jae Hyung12ORCID,Jang Hyunsung1ORCID,Bak Gwangsu1,Choi Woong3,Yun Hyewon14,Lee Eunchong1,Kim Dongjin35ORCID,Kim Jiwon36,Lee Si Young1ORCID,Hwang Yun Jeong14ORCID

Affiliation:

1. Department of Chemistry, College of Natural Sciences, Seoul National University (SNU), Seoul 08826, Republic of Korea

2. Clean Fuel Research Laboratory, Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon 34129, Republic of Korea

3. Clean Energy Research Center, Korea Institute of Science and Technology (KIST), Seoul 02792, Republic of Korea

4. Center for Nanoparticle Research, Institute for Basic Science (IBS), Seoul 08826, Republic of Korea

5. Department of Material Science and Engineering, Korea University, Seoul 02841, Republic of Korea

6. Department of Chemical and Biomolecular Engineering, Yonsei-KIST Convergence Research Institute, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749, Republic of Korea

Abstract

We demonstrate Ni–N/C is an effective electrocatalyst for the direct conversion of captured CO2 in monoethanol amine-based aqueous absorbents showing high CO faradaic efficiency (78%) and its high selectivity is maintained in various amine solvents.

Funder

National Research Foundation of Korea

Institute for Basic Science

Seoul National University

University of Seoul

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Reference56 articles.

1. IPCC, Intergovernmental Panel on Climate Change – Sixth Assessment Report, https://www.ipcc.ch/assessment-report/ar6/ , accessed 20 April 2022

2. UNFCCC, United Nations Framework Convention on Climate Change – The Paris Agreement, https://unfccc.int/process-and-meetings/the-paris-agreement/the-paris-agreement , accessed 20 April 2022

3. Integrated energy conversion and storage devices: Interfacing solar cells, batteries and supercapacitors

4. Effective energy utilization through economic development for sustainable management in smart cities

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