Predicting the right mechanism for hypervalent iodine reagents by applying two types of hypervalent twist models: apical twist and equatorial twist-Reference-Cited by-同舟云学术

Predicting the right mechanism for hypervalent iodine reagents by applying two types of hypervalent twist models: apical twist and equatorial twist

Published:2021 Issue:11 Volume:23 Page:6758-6762
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Sun Tian-Yu¹²³⁴⁵^ORCID,Chen Kai⁶⁷⁸⁹¹⁰^ORCID,Lin Qihui¹¹¹²¹³⁹,You Tingting¹²³⁴⁵,Yin Penggang¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education

2. School of Chemistry

3. Beihang University

4. Beijing 100191

5. China

6. School of Chemistry and Chemical Engineering

7. Central South University

8. Changsha 410083

9. P. R. China

10. Lab of Computational Chemistry and Drug Design

11. Hygien Sect Longhua Ctr Dis Control & Prevent

12. Joint Lab Infect Dis Prevent & Control

13. Shenzhen 518109

Abstract

Since hypervalent twist followed by reductive elimination is a general reaction pattern for hypervalent iodine reagents, mechanistic studies about the hypervalent twist step could provide significant guidance for experiments.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Guangdong Province

Natural Science Foundation of Hunan Province

Sanming Project of Medicine in Shenzhen

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP06692C

Reference37 articles.

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2. IUPAC., Compendium of Chemical Terminology, 2nd edn

3. Enhancing 2-Iodoxybenzoic Acid Reactivity by Exploiting a Hypervalent Twist

4. M. Ochiai , Hypervalent Iodine Chemistry: Modern Developments in Organic Synthesis , ed. T. Wirth , Topics in Current Chemistry, vol. 224, Springer Verlag , Berlin , 2003 , p. 5

5. Structure and stereolability of triaryliodine (III) compounds. Degenerate isomerization of 5-phenyl-5H-dibenziodole

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