Pd-Catalyzed sequential β-C(sp3)–H arylation and intramolecular amination of δ-C(sp2)–H bonds for synthesis of quinolinones via an N,O-bidentate directing group

Author:

Guan Mingyu12345,Pang Yubo12345,Zhang Jingyu12345,Zhao Yingsheng67895

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province

2. College of Chemistry

3. Chemical Engineering and Materials Science Soochow University

4. Suzhou 215123

5. China

6. College of Physics

7. Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology

8. Soochow University

9. Suzhou 215006

Abstract

An effective protocol for the synthesis of quinolinone derivatives by palladium-catalyzed sequential β-C(sp3)–H arylation and selective intramolecular C(sp2)–H/N–H amination is developed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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