Modulating intramolecular electron and proton transfer kinetics for promoting carbon dioxide conversion

Author:

Yuan Yajie12,Zhao Yazhen2,Yang Shuai3,Han Sheng1ORCID,Lu Chenbao2ORCID,Ji Huiping2,Wang Tianfu2ORCID,Ke Changchun4,Xu Qing5ORCID,Zhu Jinhui26ORCID,Zhuang Xiaodong2ORCID

Affiliation:

1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

2. The Meso-Entropy Matter Lab, State Key Laboratory of Metal Matrix Composites, School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Jiao Tong University, Shanghai, 200240, China

3. Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201210, P. R. China

4. Institute of Fuel Cells, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

5. CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201210, P. R. China

6. College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China

Abstract

An azulene modified iron porphyrin with a narrow bandgap is synthesized. When used as an electrocatalyst for CO2 reduction, it exhibits nearly 100% selectivity for carbon monoxide formation.

Funder

National Natural Science Foundation of China

Science and Technology Commission of Shanghai Municipality

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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