Effect of water frustration on water oxidation catalysis in the nanoconfined interlayers of layered manganese oxides birnessite and buserite-Reference-Cited by-同舟云学术

Effect of water frustration on water oxidation catalysis in the nanoconfined interlayers of layered manganese oxides birnessite and buserite

Published:2021 Issue:11 Volume:9 Page:6924-6932
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Bhullar Ravneet K.¹²³⁴,Zdilla Michael J.¹²³⁴^ORCID,Klein Michael L.¹²³⁴,Remsing Richard C.⁵⁶⁷⁴

Affiliation:

1. Department of Chemistry

2. Temple University

3. Philadelphia

4. USA

5. Department of Chemistry and Chemical Biology

6. Rutgers University

7. Piscataway

Abstract

Reacting out of frustration: unlike buserite, the nanoconfined interlayer of birnessite results in geometric frustration of water molecules, which decreases the Marcus reorganization energy of electron transfer and enhances water oxidation catalysis.

Funder

Army Research Laboratory

Division of Chemistry

National Science Foundation

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/TA/D0TA09635K

Reference32 articles.