Triphenylphosphine: a ligand for heterogeneous catalysis too? Selectivity enhancement in acetylene hydrogenation over modified Pd/TiO2 catalyst
Author:
Affiliation:
1. Surface Chemistry and Catalysis Group
2. Department of Chemistry
3. University of Aberdeen
4. Aberdeen
5. UK
Abstract
Triphenyl phosphine was found to modify the properties of Pd/TiO2 catalysts leading to enhanced selectivity in acetylene hydrogenation in the presence of ethylene.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2015/CY/C5CY00065C
Reference49 articles.
1. Interplay between carbon monoxide, hydrides, and carbides in selective alkyne hydrogenation on palladium
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3. The Roles of Subsurface Carbon and Hydrogen in Palladium-Catalyzed Alkyne Hydrogenation
4. Acetylene and Ethylene Hydrogenation on Alumina Supported Pd-Ag Model Catalysts
5. Factors Influencing Hydride Formation in a Pd/TiO2 Catalyst
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