The boron–boron triple bond in NHC→BB←NHC
Author:
Affiliation:
1. Fachbereich Chemie
2. Philipps-Universität Marburg
3. 35032 Marburg
4. Germany
5. Donostia International Physics Center (DIPC)
Abstract
Thorough examination of the electronic structure of the compound B2(NHCMe)2 provides convincing evidence for a BB triple bond.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01504A
Reference45 articles.
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4. Comparative Study of Phosphine and N-Heterocyclic Carbene Stabilized Group 13 Adducts [L(EH3)] and [L2(E2Hn)]
5. The boron–boron triple bond? A thermodynamic and force field based interpretation of the N-heterocyclic carbene (NHC) stabilization procedure
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