Intramolecular multi-bond strain: the unrecognized side of the dichotomy of conjugated systems-Reference-Cited by-同舟云学术

Intramolecular multi-bond strain: the unrecognized side of the dichotomy of conjugated systems

Published:2016 Issue:9 Volume:7 Page:5872-5878
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mo Yirong¹²³⁴⁵,Zhang Huaiyu¹²³⁴⁵,Su Peifeng¹²³⁴⁵,Jarowski Peter D.⁶⁷⁸⁹,Wu Wei¹²³⁴⁵

Affiliation:

1. The State Key Laboratory of Physical Chemistry of Solid Surfaces

2. Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry and College of Chemistry and Chemical Engineering

3. Xiamen University

4. Xiamen

5. China

6. University of Surrey

7. Advanced Technology Institute

8. Guildford

9. UK

Abstract

Apart from the more familiar π-conjugation, there is also significant π–π repulsion which is a kind of unrecognized intramolecular strain and can be quantified with the linear B₄H₂ model system.

Funder

Directorate for Computer and Information Science and Engineering

Western Michigan University

China Scholarship Council

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC00454G

Reference78 articles.

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3. J. F. Liebman and A.Greenberg, Strained Organic Compounds, Academic Press, New York, 1978

4. The Concept of Strain in Organic Chemistry

5. Bonding Properties of Cyclopropane and Their Chemical Consequences

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